'transition metal'
Yb
Pd
'non-innocent ligand'
'f-element'
Office: 0033 (0)1 69 33 44 02
greg.nocton(at)polytechnique.edu
2018
37. Cerium Tetra(tropolonate) and Cerium Tetra(acethylacetonate) are Not Diamagnetic but Temperature-Independent Paramagnets
Robert L. Halbach, Grégory Nocton,* Corwin H. Booth, Laurent Marond and Richard A. Andersen*
Inorg. Chem., accepted
2017
36. Metallic oxidation states and redox non-innocent ligands: between Scylla and Charybdis
Grégory Nocton*
L'Act. Chim., 2017, 424, 61
35. Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes
Mathieu Xémard, Violaine Goudy, Augustin Braun, Maxime Tricoire, Marie Cordier, Louis Ricard, Ludovic Castro, Elisa Louyriac, Christos E. Kefalidis, Carine Clavaguéra, Laurent Maron and Grégory Nocton*
Organometallics, 2017, 36, 4660
34. Electronic Structures of Mono-Oxidized Copper and Nickel Phosphasalen Complexes
Irene Mustieles Marín, Thibault Cheisson, Rohit Singh Chauhan, Christian Herrero, Marie Cordier, Carine Clavaguéra,* Grégory Nocton,* and Audrey Auffrant*
Chem. Eur. J., 2017, 23, 17240
33. Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment
Violaine Goudy, Arnaud Jaoul, Marie Cordier, Carine Clavaguéra and Grégory Nocton*
J. Am. Chem. Soc. 2017, 139, 10633-10636
• Pdf
32. Assessment of density functionals for computing thermodynamic properties of lanthanide complexes
Arnaud Jaoul, Grégory Nocton* and Carine Clavaguéra*
Chem. Phys. Chem., 2017, 18, 2688-2696
31. Effect of Cations on the Structure and Electrochemical Response of Polyoxometalate-Based Coordination Polymers
William Salomon, Grégoire Paille, Maria Gomez-Mingot,* Pierre Mialane, Jérôme Marrot, Grégory Nocton, Caroline Mellot-Draznieks, Marc Fontecave and Anne Dolbecq A.*
Cryst. Growth Des., 2017, 17, 1600-1609
30. Divalent thulium triflate: a structural and spectroscopic study
Mathieu Xémard, Arnaud Jaoul, Marie Cordier, Florian Molton, Olivier Cador, Boris Le Guennic, Carole Duboc, Olivier Maury, Carine Clavaguéra and Grégory Nocton*
Angew. Chem. Int. Ed., 2017, 54, 4266-4271
• Pdf
• Supporting information
• Cif file
• Magnetic data
29. Redox Initiated Reactivity of Dinuclear Niobium Imido Complexes
Benjamin M. Kriegel, Lara C. E. Naested, Grégory Nocton, K. V. Lakshmi, Trevor D. Lohrey, Robert G. Bergman and John Arnold*
Inorg. Chem., 2017, 56, 1626-1637
• Pdf
• Supporting information
• Cif file
• EPR data
2016
28. Synthesis and Characterization of 1,1’-diphosphaplumbocenes: oxidative ligand transfer with divalent thulium complexes
Florian Jaroschik,* Aurélien Momin, Agathe Martinez, Dominique Harakat, Louis Ricard, Xavier Frédéric Le Goff and Grégory Nocton*
Organometallics, 2016, 35, 2032-2038
• Pdf
• Supporting information
• Cif file
• EPR data
27. Tetramethylbiphosphinine Complexes of Cp*2Yb and Cp*2Sm: Solid-State Structure, Solution NMR Spectroscopy and Theoretical Calculations
Arnaud Jaoul, Carine Clavaguéra and Grégory Nocton*
New J. Chem., 2016, 8, 6643-6649
• Pdf
• Supporting information
• Cif file
• EPR data
2015
26. η5−η1 Switch in Divalent Phosphaytterbocene Complexes with Neutral Iminophosphoranyl Pincer Ligands: Solid State Structures and Solution NMR 1JYb-P Coupling Constants
Thibault Cheisson, Audrey Auffrant* and Grégory Nocton*
Organometallics, 2015, 34, 5470-5478
• Pdf
• Supporting information
• Cif file
• EPR data
25. Geometry Flexibility of Copper Iodide Clusters: Variability in Luminescence Thermochromism
Quentin Benito, Xavier Frédéric Le Goff, Grégory Nocton, Alexandre Fargues, Alain Garcia, Aurélie Berhault, Samia Kahlal, Jean-Yves Saillard, Charlotte Martineau, Thierry Gacoin, Jean-Pierre Boilot, and Sandrine Perruchas*
Inorg. Chem., 2015, 54, 4483-4494
24. Mechanochromic luminescence of Copper Iodide Clusters
Quentin Benito, Isabelle Maurin, Thibault Cheisson, Grégory Nocton, Alexandre Fargues, Alain Garcia, Charlotte Martineau, Thierry Gacoin, Jean-Pierre Boilot and Sandrine Perruchas*
Chem. A Eur. J., 2015, 21, 5892-5897
23. Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium
Grégory Nocton* and Louis Ricard
Chem. Commun., 2015, 51, 3578-3581
22. Electron Localization in a Mixed-valent Diniobium Benzene Complex
Thomas L. Gianetti, Grégory Nocton*, Stefan G. Minasian, Nikolas. N. Kaltsoyannis,* A. L. David Kilcoyne, Stosh A. Kozimor, David. K. Shuh, Tolek Tyliszczak, Robert G. Bergman* and John Arnold*
Chem. Sci., 2015, 6, 993-1003
2014
21. Carbon-Hydrogen Bond Breaking and Making in the Open-Shell Singlet Molecule, Cp*2Yb(4,7-Me2phen)
Grégory Nocton,* Corwin H. Booth, Laurent Maron, Louis Ricard, Richard A. Andersen*
Organometallics, 2014, 33, 6819-6829
20. Multiple One-electron Transfers in Bipyridine Complexes of Bisphospholyl Thulium
Léa Jacquot, Mathieu Xémard, Carine Clavaguéra, Grégory Nocton*
Organometallics, 2014, 33, 4100-4016
19. Reversible Sigma C-C Bond Formation Between Phenanthroline Ligands Activated by (C5Me5)2Yb
Grégory Nocton*, Wayne W. Lukens, Corwin H. Booth, Sergio S. Rozenel, Scott A. Medling, Laurent Maron and Richard A. Andersen*
J. Am. Chem. Soc., 2014, 136, 8626-8641
18. A Phosphasalen Nickel(III) Complex
Thi-Phuong-Anh Cao, Grégory Nocton, Louis Ricard, Xavier-Frédéric Le Goff and Audrey Auffrant*
Angew. Chem. Int. Ed., 2014, 53, 1368-1372
17. N-Aromatic heterocycles adducts of bulky [1,2,4-(Me3C)C5H2]2Sm: synthesis, structure and solution analysis Grégory Nocton* and Louis Ricard
Dalton Trans., 2014, 43 (11), 4380-4387
2013
16. The influence of the Torsion Angle in 3,3’-Dimethyl,2,2’-bipyridine on the Intermediate Valence in (C5Me5)2Yb(3,3’-Me2-bipy)
Grégory Nocton,* Corwin H. Booth, Laurent Maron, Richard A. Andersen
Organometallics, 2013, 32, 5305-5312
15. CO Activation by Diphosphine-Pt(0): Carbonate and Acetone Formation. Experimental and Mechanistic Study
Emmanuel Nicolas, Grégory Nocton*, Nicolas Mézailles
Eur. J. Inorg. Chem., 2013, 22-23, 4000-4007
Post-Doc and Graduate school papers
14. Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure and Ligand-Dependent Redox Behavior”
Andrez J., Bozoklu, G., Nocton, G., Pécaut, J., Scopelliti R., Dubois, L., Mazzanti, M.
Chem. Eur. J., 2015, 21, 15188-15200
13. Diniobium Inverted Sandwich Complexes with µ-η6:η6-arene Ligands: Synthesis, Kinetic of Formation, and Electronic Structure
Thomas L. Gianetti, Grégory Nocton, Stefan G. Minasian, Neil C. Tomson, A.L.D. Kilcoyne, Stosh A. Kozimor, David K. Shuh, Tolek Tyliszczak, Robert G. Bergman, John Arnold
J. Am. Chem. Soc. 2013, 135, 3224-3236.
12. Thermal Dihydrogen Elimination from Cp*2Yb(4,5-Diazafluorene)
Grégory Nocton, Corwin H. Booth, Laurent Maron, Richard A. Andersen
Organometallics, 2013, 32, 1150-1158.
11. Synthesis and X-Ray Structure of Ruthenium bis(acetylacetonate)(N,N,N',N'-tetramethylethylenediamine)
Robert L. Halbach, Grégory Nocton, Richard Andersen
Dalton Trans. 2012, 41, 8809-8812.
10. High energy resolution X-ray absorption spectroscopy study of uranium in varying valence states
Vitova T., Kvashnina K., Nocton G., Sukharina G., Denecke M. A., Butorin S. M., Mazzanti M., Cacciuffo R., Soldatov A., Behrends T., and Geckeis H.
Phys. Rev. B, 2010, 82.
9. Cation-cation Complexes of Pentavalent Uranyl: From Disproportionation Intermediates to Stable Clusters
Victor Mougel, Pawel Horeglad, Grégory Nocton, Jacques Pécaut, Marinella Mazzanti
Chem. Eur. J., 2010, 16, 14365-14377.
8. Ligand Assisted Cleavage of Uranium Oxo-Clusters
Grégory Nocton, Jacques Pécaut, Yaroslav Filinchuk, Marinella Mazzanti
Chem. Commun. 2010, 46, 2757-2759.
7. Synthesis, Structure and Bonding of Stable Complexes of Pentavalent Uranyl
Grégory Nocton, Pawel Horeglad, Valentina Vetere, Jacques Pécaut, Lionel Dubois, Pascale Maldivi, Norman M. Edelstein, Marinella Mazzanti
J. Am. Chem. Soc. 2010, 132, 495-508.
6. Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed-Valent Uranyl Complex by Cation-Cation Interactions
Victor Mougel, Pawel Horeglad, Grégory Nocton, Jacques Pécaut, Marinella Mazzanti
Angew. Chem. Int. Ed. 2009, 48, 8477-8480. (Inside Cover).
5. Water Stability and Luminescence of Lanthanide Complexes of Tripodal Ligands Derived from 1,4,7-triazacyclononane: pyridine carboxamide versus picolinate donors
Grégory Nocton, Aline Nonat, Christelle Gateau, Marinella Mazzanti
Helvetica Chimica Acta 2009, 92, 2257 (invited issue).
4. Pentavalent Uranyl Stabilized by a Dianionic Bulky Tetradentate Ligand
Pawel Horeglad, Grégory Nocton, Yaroslav Filinchuk, Jacques Pécaut, Marinella Mazzanti
Chem. Commun. 2009, 1843-1845.
3. Polynuclear Cation-Cation Complexes of Pentavalent Uranyl: Relating Stability and Magnetic Properties to Structure
Grégory Nocton, Pawel Horeglad, Jacques Pécaut, Marinella Mazzanti
J. Am. Chem. Soc. 2008, 130, 16633-16645.
2. A New Nitrido-Centred Uranium Azido Cluster obtained from a Uranium Azide.
Grégory Nocton, Jacques Pécaut, Marinella Mazzanti
Angew. Chem. Int. Ed. 2008, 47, 3040-3042 (Inside cover).
1. Self-Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low Valent Uranium
Grégory Nocton, Fabien Burdet, Jacques Pécaut, Marinella Mazzanti
Angew. Chem. Int. Ed. 2007, 43, 7584.